The whole book is available online now.
I have a physical copy though, which I've found very difficult to read (and consequently have only got a couple of chapters in) - not because the ideas were difficult, but because I had a hard time getting past all the bombast. Wolfram was apparently utterly convinced of the novelty of his ideas, and felt the need to spend much the book talking about how new and important they are, without ever acknowledging any of the work which has taken place in much the same areas, or the ideas which were already quite well-established when he started.
He is also a little too ready to point at a pretty picture which looks a bit like a snowflake, for instance, and say 'Look! New insight into how snowflakes work! See'
This is a pain, because I still suspect that there may well have been new and important things being said, they were just obscured (for me) by all the bits about how NEW! and IMPORTANT!
everything in the book apparently was. I hope to get back to reading it before too long, anyway.
Even if my suspicion is wrong, he's definitely collected together a whole bunch of interesting ways to make pretty pictures!