OpenCV comes with a face detection example that places a rectangle over faces. faces[i].x and faces[i].y will give you the top left of the face and faces[i].width and faces[i].height will give you the area of the rectangle.
If you want to find the center of a face use:
xCenter = faces[i].x+faces[i].width/2;
yCenter = faces[i].y+faces[i].height/2;